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In thermodynamics, the Gibbs free energy is a thermodynamic potential that can be used to calculate the maximum amount of work, other than pressure–volume work, that may be performed by a thermodynamically closed system at constant temperature and pressure. It also provides a necessary condition for processes such as chemical reactions that may occur under these conditions. The Gibbs free energy is expressed as
where: is the internal energy of the system
is the enthalpy of the system
is the entropy of the system
is the temperature of the system
is the volume of the system
is the pressure of the system.
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