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This topic has appeared in the English Wikipedia rankings 1 time. It first appeared on 2026-08-22 and was most recently seen on 2026-08-22.
In classical statistical mechanics, the H-theorem, introduced by Ludwig Boltzmann in 1872, describes the tendency of the quantity H to decrease in a nearly-ideal gas of molecules. As this quantity H was meant to represent the entropy of thermodynamics, the H-theorem was an early demonstration of the power of statistical mechanics as it claimed to derive the second law of thermodynamics—a statement about fundamentally irreversible processes—from reversible microscopic mechanics. It is thought to prove the second law of thermodynamics, albeit under the assumption of low-entropy initial conditions.
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