Why is "2,2,2-cryptand" trending?
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- Date: 2026-03-18 02:00:22
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Wikipedia Overview
[2.2.2]Cryptand is the organic compound with the formula N(CH2CH2OCH2CH2OCH2CH2)3N. This bicyclic molecule is the most studied member of the cryptand family of chelating agents. It is a white solid. Many analogous compounds are known. Their high affinity for alkali metal cations illustrates the advantages of "preorganization", a concept within the area of supramolecular chemistry.
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Search Interest Perspective
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Catalytic and stoichiometric stepwise conversion of side-on bound dinitrogen to ammonia mediated by a uranium complex - Nature
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Redox‐Switchable Poly‐Lewis Acids Allow the Controlled Release of Guests - Wiley Online Library
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Catenated (Bi)n (n=2, 3, 4) Complexes with Formally Monovalent Bismuth Centres - Wiley Online Library
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Valence-delocalized trithorium nanocluster superatoms with open-shell exalted diamagnetism - Nature
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Nucleophilic Attack at Pentaarsaferrocene [Cp*Fe(η5‐As5)]—The Way to Larger Polyarsenide Ligands - Wiley Online Library
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Self-assembly of an anion receptor with metal-dependent kinase inhibition and potent in vitro anti-cancer properties - Nature
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Dinitrogen Reduction and Functionalization by a Siloxide Supported Thulium-Potassium Complex for the Formation of Ammonia or Hydrazine Derivatives - Wiley Online Library
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Magnetic properties of monomeric and polymeric stannolediide yttrium and erbium complexes - Nature
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Ground and excited electronic structures of electride and alkalide units: The cases of Metal-Tren, -Azacryptand, and -TriPip222 complexes - Wiley Online Library
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Diaryl Bismuthides and Acyl Bismuthanes Enable Visible-Light-Induced Reversible Carbon Monoxide Insertion and Extrusion - Nature
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Cyclo‐P5− Revisited: The Surprisingly Stable Uncoordinated Pentaphospholide Anion - Wiley Online Library
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Efficient reduction method enables access to rare-earth telluride clusters - Nature
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Self-Assembled Anion-Binding Cryptand for the Selective Liquid–Liquid Extraction of Phosphate Anions - Wiley Online Library
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2 reactions activated by Lewis Base Phase transfer catalysts - Nature
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Theoretical and preliminary experimental investigations on the interactions between sugar cryptand and treosulfan - Nature
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Reduction-Induced C─C Cleavage and Site-Specific Hydrogenation of a Highly Strained Bilayer Spironanographene - Wiley Online Library
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Alkali metal reduction of alkali metal cations - Nature
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Synthesis and Reactivity of a Cyclooctatetraene‐Like Polyphosphorus Ligand Complex [Cyclo‐P8] - Wiley Online Library
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An efficient multi-gram access in a two-step synthesis to soluble, nine-atomic, silylated silicon clusters - Nature
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Experimental and computational studies on possibility of using glucose diazacrown cryptand as a carrier for anticancer drugs busulfan and lomustine - Nature
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Actinide Pnictinidene Chemistry: A Terminal Thorium Parent-Arsinidene Complex Stabilised by a Super-Bulky Triamidoamine Ligand - Wiley Online Library
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Uranium-stibinidiide, -stibinidene, and -stibido multiple bonds and uranium-nitride formation from multimetallic diuranium-distibene-mediated dinitrogen cleavage - Nature
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Nucleophilic Attack at Pentaarsaferrocene [Cp*Fe(η5‐As5)]—The Way to Larger Polyarsenide Ligands - Wiley Online Library
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A theoretical mechanistic study of [K ⊂ [2.2.2]]+ enantiomerization - Wiley Online Library
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Selective Hydrogen Isotope Exchange Catalysed by Simple Alkali‐Metal Bases in DMSO - Wiley Online Library
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Lanthanide‐Based Molecular Magnetic Semiconductors - Li - 2024 - Angewandte Chemie International Edition - Wiley Online Library
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All-Metal Sandwich Is Now On The Menu - C&EN
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Researchers develop novel alkaline anion exchange membrane - Phys.org
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Self-assembly of dynamic orthoester cryptates - Nature
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The Cyanoketenyl Anion [NC3O]− - Krischer - 2024 - Angewandte Chemie International Edition - Wiley Online Library
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Synthesis, Isolation, and Reactivity Studies of ‘Naked’ Acyclic Gallyl and Indyl Anions - Wiley Online Library
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Peroxide Dianion Finds A Stable Home - C&EN
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Open questions on bonding involving lanthanide atoms - Nature
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Triamidoamine thorium-arsenic complexes with parent arsenide, arsinidiide and arsenido structural motifs - Nature
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Engineering electronic structure to prolong relaxation times in molecular qubits by minimising orbital angular momentum - Nature
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Actinide chemistry expands to new oxidation states - C&EN
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Triamidoamine–Uranium(IV)-Stabilized Terminal Parent Phosphide and Phosphinidene Complexes - Wiley Online Library
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Crystallographic and spectroscopic characterization and reactivities of a mononuclear non-haem iron(III)-superoxo complex - Nature
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Self-organized intestinal epithelial monolayers in crypt and villus-like domains show effective barrier function - Nature
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Chemists Discover New Oxidation State of Plutonium - Sci.News
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Vampire: The Masquerade Bloodlines 2 Is Finally Emerging from Its Crypt and Is Making Its Way to PC and Consoles on October 21 - The FPS Review
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Lanthanides Topple Assumptions - C&EN
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Lanthanum Does Form Stable Molecular Compounds in the +2 Oxidation State - Wiley Online Library
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General Hospital 2-Week Spoilers March 10-21: Drew Wrecks Family Crypt and Dante Rocked - Soap Dirt |
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